Identification of the Conformation of Individual Molecules by Scanning Tunneling Microscopy

نویسندگان

  • Hongbin Fang
  • Leanna C. Giancarlo
  • George W. Flynn
چکیده

In the gas phase the carboxyl group of an n-carboxylic acid molecule may adopt a number of different conformations. Upon adsorption on a solid surface, however, the carboxyl group usually assumes one of two possible configurations. Atomically resolved STM images show that the conformations of the carboxyl groups in 12-bromododecanoic acid and 2-bromohexadecanoic acid molecules differ when adsorbed at the liquid (phenyloctane)-solid (graphite) interface.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Scanning tunneling microscopy of the formation, transformation, and property of oligothiophene self-organizations on graphite and gold surfaces.

Two alkyl-substituted dual oligothiophenes, quarterthiophene (4T)-trimethylene (tm)-octithiophene (8T) and 4T-tm-4T, were used to fabricate molecular structures on highly oriented pyrolytic graphite and Au(111) surfaces. The resulted structures were investigated by scanning tunneling microscopy. The 4T-tm-8T and 4T-tm-4T molecules self-organize into long-range ordered structures with linear and...

متن کامل

Scanning tunneling microscopy manipulation of complex organic molecules on solid surfaces.

Organic molecules adsorbed on solid surfaces display a fascinating variety of new physical and chemical phenomena ranging from self-assembly and molecular recognition to nonlinear optical properties and current rectification. Both the fundamental interest in these systems and the promise of technological applications have motivated a strong research effort in understanding and controlling these...

متن کامل

Direct Determination of the Chirality of Organic Molecules by Scanning Tunneling Microscopy

Scanning tunneling microscopy (STM) has been used to study the chiral molecules (R)/(S)-2-bromohexadecanoic acid at the liquid/solid interface. When adsorbed onto the basal plane of graphite, these molecules segregate on the surface into domains of pure R or S enantiomers. The atomic resolution obtained in the STM images of these species allows a direct assignment of the chirality of individual...

متن کامل

Experimental observation of a band gap in individual Mn12 molecules on Au(111)

The authors report on the electronic properties of individual molecules of two Mn12 derivatives chemically grafted on the functionalized Au 111 surface studied by means of ultrahigh vacuum scanning tunneling microscopy/spectroscopy at room temperature. Reproducible current-voltage curves were obtained from both Mn12 molecules, showing a well defined wide band gap. In agreement with the tunnelin...

متن کامل

Imaging and Characterization of Molecules and One-Dimensional Crystals Formed within Carbon Nanotubes

The imaging and characterization of individual molecules and atomically thin, effectively one-dimensional crystals of rock salt and other halides encapsulated within single-walled carbon nanotubes are reviewed in this article. These species were imaged by conventional and super-resolved high-resolution transmission electron microscopy and by scanning tunneling microscopy, revealing the detailed...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1999